Based on the data of 1995-2014 from the United Nations Commodity Trade Database, this paper firstly analyzes the trade valume of high-tech products between China and Russian Federation(abbreviation:Russia). We analyze on the present situation of the high-tech products trade and the trade structure. It is concluded that the number scale of the high-tech products trade of this two countries is incomparable, because China attaches great importance to the high-tech product development, and its trade volume is among the world's highest. At the same time, Russia's trade structure is still mainly based on the primary products, high-tech products trade volume is relatively weak, but recent years its growth rate demonstrates upgrade tendency.