Abstract: As the strategy of Chinese Enterprises Going Out is carried forward, Chinese Enterprises Walking Into Africa is one of the most imporatnt strategies. The economic cooperation and communication between China and South Africa has developed into a profounding level, thus to know and be familiar with the labor and social security law system has been the important weapon for Chinese Enterpriese Going Out. South Africa is one of the most developed economic countries of Africa, its labor contract legal system has learned the essences from the Euro-American law, at the same time, it has the distinctive native characteristics. By comparing with the Chinese labor contract legal system, we found that the regulations about the form, the content and the types of South African labor contract legal system are tending to protect the employees’ lawful rights and interests. If the employer doesn’t follow the rules of South African labor laws when dismissing the employees, he or she will suffer the adverse impact and a great economic loss.